b336a53425 Note that in a typical solidification or crystallization process, the thermodynamic driving force is dictated by the degree of supercooling. Discontinuity[edit]. ^ Atkins, P.W., Physical Chemistry (W.H. Wiley, New York. Such first-order transitions must proceed by the advancement of an interfacial region whose structure and properties vary discontinuously from the parent phase.[1][2][3][4]. doi:10.1039/DF9490500040. 28: 16. In another sense, it is not in equilibrium. And homogeneous conditions for the transport process can only exist for spherical, cylindrical, or infinite plane surfaces.
In general, the supersaturation is greatest at its corners. ^ Burton, W. "The influence of dislocations on crystal growth". Chivilikhin, "Model of porous aluminum oxide growth in the initial stage of anodization", Nanosystems: physics, chemistry, mathematics, October 2013, Volume 4, Issue 5, pp 585 ^ Burton, W. The interface form determines the additional free energy for each volume of crystal growth. ^ Jackson, K.A. Some suggestions: Go back to the last page Go to the home page .. Lattice arrangement in metals often takes the structure of body centered cubic, face centered cubic, or hexagonal close packed.
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